Semicarbazone of 2-Aminonicotinaldehyde With Cu(II), Ni(II), Co(II), Zn(II), Cd(II) and Pd(II) : Synthesis and Structure

J. Ramanuja Swami¹* and B. Swami²

¹Department of Chemistry, Government College, ParkaI-506 164 India.

²Department of Chemistry, KU

ABSTRACT:

Coordination compounds formed by the inteiaction of Cu(II), Ni(II), Co(II), Zn(II), Cd(II) and Pd(ll) with neutral tridentate ligand-semicarbazone of 2-aminonicotinaldehyde (SCANA) have been prepared. Stoichiometrics of the complexes have been established by metal estimations gravimetrically. The complexes isolated in the solid state have been characterized by molar conductance, magnetic susceptibility, thermal, electronic, infrared and ESR spectral measurements. Tentative stereochemistries of the complexes in the solid state are discussed.

KEYWORDS:

Coordinatio; Semicarbazone; Cu(II), Ni(II), Co(II), Zn(II), Cd(II) and Pd(II)

Download this article as: 

Copy the following to cite this article: Swami J. R, Swami B. Semicarbazone of 2-Aminonicotinaldehyde With Cu(II), Ni(II), Co(II), Zn(II), Cd(II) and Pd(II) : Synthesis and Structure. Orient J Chem 1993;9(1).

Copy the following to cite this URL: Swami J. R, Swami B. Semicarbazone of 2-Aminonicotinaldehyde With Cu(II), Ni(II), Co(II), Zn(II), Cd(II) and Pd(II) : Synthesis and Structure. Orient J Chem 1993;9(1). Available from: http://www.orientjchem.org/?p=38347