Synthesis and characterization of lanthanum oxide  and lanthanumoxid carbonate nanoparticles from thermalizes of [La(acacen)(NO₃)(H₂O) complex

Introduction

In recent years, the synthesis of inorganic materials with specific size and morphology has attracted considerable attention. Their excellent physical and chemical properties in various fields, such as solar cells, catalysis, photo detectors, sensors, light emitting diodes and laser communication, have made them attractive^1–4 and promising materials. It is well documented that materials with nano-scale grain size show different properties relative to the same material in bulk form ^5–7. Preparation of various nano-materials have many different synthetic approaches such as chemical vapor deposition (CVD), thermal evaporation, chemical bath deposition,laser ablation, hydrothermal, homogeneous precipitation in an organic matrix,sonochemical and sol–gel method ^8–15.The synthesis, production and manipulation of materials on the Nano scale is one of the favorite areas of research which also attracts the industrialists for designing and fabricating new functional materials with novel special properties ^1,2. Among the lanthanides, lanthanum has been extensively examined for its unique properties^7–12 and lanthanum has been synthesized in various compositions such as La(OH)₃¹³, LaF₃⁵,La₂(CO₃)₃¹⁴, LaPO₄^15–17, LaBO₃¹⁸, LaOF¹⁹,La₂Sn₂O₇²⁰,La₂O₃²¹ nanoparticles.

Lanthanum oxide (La₂O₃) powders have a lot of attractive properties for industrial and technological applications such as: 1- Nanometer lanthanum oxide can be used in piezoelectric materials to increase product piezoelectric coefficients and improve product energy conversion efficiency;  2- Nano-lanthanum oxide can be used for the manufacture of precision optical glass, high-refraction optical fiber, all kinds of alloy materials; 3- Nano-lanthanum oxide can be used for the preparation of organic chemical products catalysts, and in automobile exhaust catalyst; Nanometer Lanthanum oxide can improve the burning rate of propellant, is a promising catalyst; 4-As regards the photoelectric conversion efficiency of nano-lanthanum oxide is high,   it can be used in light-converting agricultural film; 5- Also, nano-lanthanum oxide can be used in electrode materials and in light-emitting material (blue powder), hydrogen storage materials, laser materials etc.

In the present work, we report the synthesis of  [La(acacen)(NO₃)(H₂O)](1), then this compound has been convert to Lanthanum oxides nanoparticle as La₂CO₅ at 600°C and La₂O₃ at 900°C.

Experimental

Material and Characterization

All chemicals and solvents were reagent grade or better, obtained from Merck, and used without further purification.

Infrared spectra (4000–250 cm⁻¹) of solid samples were taken as 1% dispersion in KBr pellets using a JASCO FT-IR 460 PLUS. Electronic absorption spectra in DMF solution were taken at room temperature on a JASCO 7850 spectrometer. Cyclic voltammograms were recorded using a SAMA 500. Three electrodes were utilized in this system: a glassy carbon working electrode, a platinum wire auxiliary electrode and an Ag wire reference electrode. The glassy carbon working electrode was manually cleaned with 1-μm diamond polish prior to each scan. The supporting electrolyte, 0.1 M tetrabutylammonium hexafluorophosphate (TBAH), was recrystallized twice from ethanol-water (1/1) and vacuum-dried at 110◦C overnight. A sweep rate of 100–500 mVs⁻¹ was used for all the scans. Ferrocene was used as an internal standard to compensate for the junction potential variability among experiments.

The thermal behavior was measured with a PL-STA 1500 apparatus. XRD analysis was conducted on a Philips diffractometer of X’pert company with graphite monochromatic Cu Kα radiation (λ = 1.54056 Å). The crystallite sizes of selected samples were estimated using the Scherrer method.

SEM images of the samples were collected on Philips XL30 equipped with an EDX microanalysis (TarbiatModares Uni.).

Synthesis of [La (acacen) (H₂O) (NO₃)]

To a methanolicsolution (10 ml) of La (NO₃) ₃ (0.1 M) was added dropwise aqueous solution acetylacetonatoethylenediamine (0.1 M). The resulting solution was stirred at 55–60◦C for 2h. The solid (desired product) was collected by suction filtration, washed with MeOH solution, then air dried (Yield %34). Anal.Calc: C, %32. 22; H, %5.86,; N, %9. 4). Found: C, 32.12; H, 5.73; N, 9.54.IR (KBr, cm⁻¹): 3419 and 2928 ν(CH), 1644 ν(N-O), 1530-  ν(C=C) and ν(C=N),3454 ν(O-H), 1303 ν(conjugated NO₃^–), 900ν(C-O)

Synthesis of nanoparticles (La₂CO₅ (2) and La₂O₃ (3))

Lanthanum oxide nanoparticles were prepared from [La (acacen) (H₂O) (NO₃)] (1) using the physical method. First 1.0 g of compound (1)dissolved in  oleic acid solution (5mL) as a surfactant, then calcinated at 600˚C and 900˚Cfor 4h,to get La₂CO₅ and La₂O₃ nanoparticles respectively.  The final products were collected and washed with distilled water and absolute ethanol several times, dried in air and kept for further characterization.

Results and Discussion

FT-IR spectroscopy

The broadbands at 2600-3000 cm^-1and 1712 cm⁻¹ assigned to stretching vibration of O-H and C=O groups in oleic acid respectively (Fig 1a).As it can be observed in Fig.1 all the bands of the oleic acid and [La (acacen) (H₂O) (NO₃)](1) were disappeared when the product was calcinated in 900 °C (Fig1c) and only broad band was appeared that attributed to lanthanum oxide (Fig1c). The strong band at 500 cm^-1 is assigned to the ν(La-O), indicating formation of La₂O₃(3).

Strong band sat 1585,1505 and 1625cm^-1, related to the stretching vibrations ofC = C, C = N, C = O can be shared onacacenlig and. And stretching frequency observed in the1374 cm^-1at attributed to NO₃^–group²². Weak absorptions in there gion 3158 and 3226 cm^-1assigned to N-Hvibrations of the acacen ligand^22,23.

FT-IRspectra of oleic acid showed in the Fig1b. The broad band observed at 2925-2000 cm^-1, attributed to overlap of stretching vibration frequency of the acidic OHscrew with CH bands. The bonds observed at3006 cm^-1,1711cm^-1,  1378 cm^-1 and 1465 cm^-1assign to CH, C=O,  CH₂andCH₃groups, respectively.

Figure 1: FT-IR spectra of a) oleic acid  b) [La (acacen) (H2O) (NO3)] (1) c) La2O3 (3) in KBrpellets.   Click here to View figure

 

Electronic Excitation Study

The electronic spectrum of the [La (acacen) (H₂O) (NO₃)] (1)showed in Fig2. Absorption bands in 217 and 319 nm can be assigned to the intraligand π→π* transition of the aromatic ring and n→π* transition of the acacen and nitrate ligands, respectively. There was any transition in visible region due to Lanthanum (III) has d⁰ electron configurations.

Figure 2: UV-vis absorption spectra of [La(acacen)(H2O)(NO3)](5×10-5M) in DMF(1)   Click here to View figure

 

Electrochemical Studies

Cyclic voltammetry was performed in an DMF solution of [La(acacen)(H₂O)(NO₃)](1) with 0.1 M TBAH as a supporting electrolyte at scan rate 100-500 mV s^-1 (Fig. 3). In this voltammogram, two quasi-reversible reduction couples at -0.458 and -0.690 V are assigned to the reduction of acacen ligand, by analogy to other acacen complexes²⁴. In comparison with free acacen, the reduction couples shift to more positive potentials due to the coordination of acacen ligand to the La(III) center.

Figure 3: Cyclic voltammogram of [La(acacen)(H2O)(NO3)](1) in DMF,  0.1 M TBAH as a supporting electrolyte   Click here to View figure

 

X-ray Diffraction

Fig 4 and 5 show the representative XRD pattern of  La₂CO₅ in the absence and presence of oleic acid at 600°C respectively.  It is obvious that all the diffraction peaks can be indexed to orthorhombic phase La₂CO₅ (LCSD Card Number 4242).Compared with the standard diffraction pattern. Maximum diffraction observed at 2θ=29.67° and (103) as miller indices, Fig 4. In addition, the distance between crystalline planes is d=3Ų⁵. Also the intense and sharp diffraction peaks with any signals of impurities were attributed to high purity of the product.As can be seen in Fig 5.maximum diffraction is in 2θ=29.90° with (103) as miller indices and d=3.1 Å, with addition of oleic acid.

Figure 4: XRD pattern of La2CO5 at 600°C, compared with standard sample   Click here to View figure

 

Figure 5: XRD pattern of La2CO5 in presence of oleic acid at 600°C, compared with standard sample   Click here to View figure

 

Also particle size for several diffraction and average crystallite size that were measured from the XRD data based on Debye- Scherrerʼequation for La₂CO₅ in absence and presence of oleic acid at 600°C show in Table 1 and 2 respectively. As can be seen in Table 1, the compound has nano-sized in the range of nanoparticles (below 100 nm)²⁵.

Table 1: Particle and average crystallite size of La₂CO₅in absence of oleic acid at 600°C

2θ	B	Size(nm)	Average size(nm)
3.71	0.006	23.1
22.92	0.009	17.32	25.02
29.67	0.005	34.65

 

Table 2: Particle and average crystallite size of La₂CO₅in presence of oleic acid at 600°C

2θ	B	Size(nm)	Average size(nm)
3.77	0.007	19.8
22.95	0.013	11.55	15.58
29.90	0.010	15.4

 

[La(acacen)(H₂O)(NO₃)] calcinated to La₂O₃ in a furnace at 900 C°.Fig 6.Show XRD pattern of La₂O₃ at 900°C.Nano lanthanum oxide has orthorhombic system with diffraction maximum intensity at 2θ =39.80 and Miller indices (1 1 1) with distance between the plates d= 2.98Å (Table 3).

Figure 6: XRD pattern of La2O3 at 900°C, compared with standard sample   Click here to View figure

 

Table 3: Particle and average crystallite size of La₂O₃at 900°C

2θ	B	Size(nm)	Average size(nm)
15.94	0.015	86.62
28.68	0.019	36.47	56.43
39.80	0.006	46.2

 

Surface Morphology

The morphology of the La₂CO₅ nanoparticles was characterized using scanning electron microscope (SEM) at 600°C. Fig. 7 and 8 show the SEM images of La₂CO₅ in absence and presence of oleic acid respectively. As can be seen the images are clear examples and nano-carbonateoxiderelatively spherical, porous and beneath the high porosity for use as a catalyst for much is suitable. So that the particle size is found 29.0-35.73 nm and 22.33-26.89 nm respectively that in order to the effect of surfactants on the image more uniform and stronger link between particle surface area that can provide a better view.

Figure 7: SEM images of La2CO5 at 600°C   Click here to View figure

 

Figure 8: SEM images of La2CO5in presence of oleic acid at 600°C   Click here to View figure

 

La₂O₃ have spherical shape with porous surface and particle size 24.56- 13.40nm. Fig 9.

Figure 9: SEM imagesLa2O3 at a=700, b=800, c=900˚C   Click here to View figure

 

Conclusion

Metals,rare earths, has a strong tendency to combine with non-metallic element such as oxygen, nitrogen, carbonandhydrogen, and various factors such as geometry and central atom, the structural features of the ligand molecules, with a solvent can play key roles in the formation of structures them.

The nano-sized particles have different properties than the bulk material can be explained by the fact that the smaller the particle size, then umber of at swill be a higher.
As a result,the surface energy of atoms within a material volume with a different energy and this will cause different properties. The unique properties of nano meter particles, not only because of their high level, but also for other reasons such as changes in the crystal lattice, the link between nuclear energy and so is also relevant. Its hould be noted that the production of nano-materials and the geometric arrangement of atoms is consistent with the changes in particle size,particle size reduction increases the effect of the level. Increased surface to volume ratio of nanoparticles causes the atom sin the surface atoms than the particle size, the particles have physical properties. This feature greatly increases there activity of nanoparticles.

In summary,  we prepared Lanthanum oxide nanoparticles in the presence and absence Oleic acid as a surfactant. The size of these nanoparticles was measured using XRD and SEM. The images of nanolanthanumoxide at elevated temperatures (600,700, 800 and 900ºC)observed that in all the images of the particles are almost spherical, with uniform and porousorphology and particle size are almost identical.

Acknowledgments

The authors are grateful to the University of Sistanand Baluchestan University for partial financial support.

References:

1. Singh,V.P.; Singh,R.S.; Thompson,G.W.;Jayaraman,V.; Sanagapalli,S.;Rangari, V.K.Sol. Energy Mater. Sol. Cells2004, 81, 293-303
   CrossRef
2. Shahverdizadeh,G.H.;Morsali,A.J. Inorg. Organomet.Polym.2011, 21, 694-699
   CrossRef
3. Payehghadr,M.;Safarifard, V.; Ramazani, M.; Morsali, A. J. Inorg. Organomet.Polym.2012,22, 543-548.
   CrossRef
4. Hashemi, L.; Hosseinifard, M.; Amani, V.; Morsali, A.J. Inorg. Organomet.Polym. 2013, 23, 519-524.
   CrossRef
5. Marban, G.; Lopez, A.; Lopez, I.; Valdes-Solis, T.Appl. Catal.B Env.2010, 99, 257
   CrossRef
6. Valdes-Solis, T.; Marban, G.; Fuertes, A.B. Catal. Today2006, 116, 354-360.
   CrossRef
7. Jones, S.D.; Neal, L.M.;  Everett, M.L.;Hoflund, G.B.; Weaver, E.H.H. Appl. Sur. Sci.2010, 256, 7345-7353.
   CrossRef
8. Wu, Y.; Yang, P.Chem. Mater. 2000, 12, 605-607.
   CrossRef
9. Iijima, S.Nature1991, 354, 56-58.
   CrossRef
10. Morales, A.M.;Lieber, C.M. Science.1998, 279, 208-211.
    CrossRef
11. Suciu, C.; Gagea, L.; Hoffmann, A. C.; Mocean, M.Chem. Eng. Sci. 2006, 61, 7831-7835.
    CrossRef
12. Salavati-Niasari, M.; Hosseinzadeh, G.;Davar, F. J. Alloys Compd. 2011, 509, 134-140.
    CrossRef
13. Ranjbar, M.; Çelik, Ö.;MahmoudiNajafi, Sheshmani, S.H.,AkbariMobarakeh, N.J. Inorg. Organomet.Polym. 2012, 22, 837-844
    CrossRef
14. Ranjbar, M.; Malakooti, E.; Sheshmani, S.J. Chem.2013, Vol. 2013, Article ID 560983, 6 pagesdoi: 10.1155/2013/560983
    CrossRef
15. Khorasani-Motlagh, M.; Noroozifar, M.; Ahanin-Jan, A.J. Iran. Chem. Soc. 2012, 9, 833-839.
    CrossRef
16. Averbuch-Pouchatand M. T.;Durif, A.World Scientific Publishing Co. Pte.Ltd., Singapore City, 1996.
17. Hammas, I.;Horchani-Naifer K.; Ferid, M.Journal of Rare Earths, 2010,28,. 3, 321-328.
    CrossRef
18. Meiser, F.; Cortez, C.; Caruso, F.AngewandteChemie, 2004, 43,. 44, 5954-5957.
    CrossRef
19. Onoda, H.;Nariai, H.;Moriwaki, A.; Maki, H.; Mo- tooka, I. J. Mat.Chem, 2002, 12, . 6, 1754-1760 .
20. Onoda, H.; Funamoto, T.Adv. Mat.Phy. andChem, 2012, 2,. 1, 50-54.
21. Rajesh, K.; Shajesh, P.; Seidei, O.; Mukundan, P.;Warrier, K. G. K. Adv. Fun. Mat, 2007, 17,. 10, 1682-1690
    CrossRef
22. Onoda, H.; Taniguchi, K.; Tanaka, I., Micro and Meso. Mat.,2008, 109,. 1-3, 193-198.
23. Alkadasi, N. A. N.; Orient. J. Chem., 2014,.30(3), 1179-1182.
    CrossRef
24. Onoda, H.; Matsui, H.; Tanaka, I.Mat. Sci. Eng. B,2007, 141, No. 1-2, 28-33.
    CrossRef
25. Parimalagandhi, K.; Vairam, S.; Orient. J. Chem., 2014,.30(4), 1957-1963.
    CrossRef

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