ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Influence of Chloramine-T on the Thermodynamics of Clouding Behaviour of Non Ionic Surfactant Triton X-114

A. A. Patil1 and T. J. Patil2  

Department of Chemistry, Z.B.Patil College, Deopur, Dhule - 424 002 (India).

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ABSTRACT:

The phenomenon of solubilization of nonionic surfactant TritonX-114 has been studied through the influence of additive Chloramine-T in aqueous medium by measuring the cloud points (CP) of the pure surfactant and with Chloramine-T. The CP of pure surfactant found to be increased with increased concentration of TritonX-114. The CP of mixed system shows increasing trends with increased Chloramine-T. This is mainly due to increased micelle concentrations. The influence of Chloramine-T on the cloud point of TritonX-114 is a clear indication that the phenomenon of clouding is associated with the different micelles coalescing. Considering cloud point as threshold temperature of the solubility, the thermodynamic parameters of clouding process (DG0cl , DH0cl and DS0cl ) have been evaluated using

KEYWORDS:

Micellization; Cloud Point (CP); TritonX-114 (TX-114); Chloramine-T (CAT); Phase Separation Model

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Patil A. A, Patil T. J. Influence of Chloramine-T on the Thermodynamics of Clouding Behaviour of Non Ionic Surfactant Triton X-114. Orient J Chem 2010;26(2).


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Patil A. A, Patil T. J. Influence of Chloramine-T on the Thermodynamics of Clouding Behaviour of Non Ionic Surfactant Triton X-114. Orient J Chem 2010;26(2). Available from: http://www.orientjchem.org/?p=24195



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