Electrochemical redox of Cd(II) mediated by activated carbon modified glassy carbon electrode

W. T. Tan, M.M. Radhi*, M. Z. Abrahman and A. Kassim

Department of Chemistry, University Putra Malaysia, 43400 UPM, Serdang, Selangor D.E., (Malaysia).

ABSTRACT:

The use of a glassy carbon electrode (GCE) modified by activated carbon (AC) mediates the redox of (CdCl2 ) in 0.1 M aqueous solution of potassium chloride (KCl) supporting electrolyte. During cyclic voltammetry, two oxidation and two reduction current peaks of Cd2+ were appearing at +0.4, - 0.6, +0.6 and -1.8V respectively, versus Ag/AgCl. The redox current of Cd2+ was enhanced by two folds at AC modified GCE and about five folds in acidic media. The oxidation peak of Cd2+ was shifted to lower potential by approximately 5mV and for the reduction peak was shifted to 0 mV when AC modified GCE in acidic pH. The sensitivity under condition of cyclic voltammetry was significantly dependent on pH, concentration of AA and temperature. Interference with Cd2+ was observed in different metal ions, such as Cu2+ Mn2+ and Hg2+. The current enhancement appeared and causes further increase in the two reduction peaks and one of oxidation peak of Cd2+, in contrast the other oxidation current peak decrease when increase the concentration of the interference metals. The surface charge determined by chronocoulometry (CC) of Cd2+ at AC/GCE in presence of AA solution was more conductive than use of GCE. Diffusion coefficient determined by chronoamperometry (CA) for Cd2+ at AC/GCE in presence of AA was promising results.

KEYWORDS:

Activated carbon; GC electrode; CdCl2; ascorbic acid; cyclic voltammetry

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Copy the following to cite this article: Tan W. T, Radhi M. M, Abrahman M. Z, Kassim A. Electrochemical redox of Cd(II) mediated by activated carbon modified glassy carbon electrode. Orient J Chem 2010;26(2).

Copy the following to cite this URL: Tan W. T, Radhi M. M, Abrahman M. Z, Kassim A. Electrochemical redox of Cd(II) mediated by activated carbon modified glassy carbon electrode. Available from: http://www.orientjchem.org/?p=11521