Influence of Ionic Strength of Medium on Stability Constants of Cu(II) Complex of 2-Amino-5-Chloro Benzene Sulphonic Acid at 301K

S. D. Deosarkar, M. L. Narwade, V. J., V. V. Hiwase and K. M. Khedkar  

Department of chemistry, S. F. S. College, Seminary Hills, Nagpur - 440 006 (India). 2-3Vidyabharti Mahavidyalaya, Amravati-444.

ABSTRACT:

The proton-ligand stability constants and metal-ligand stability constants of 2-Amino-5-Chloro Benzene Sulphonic Acid and its complexes with Cu (II) metal ions were investigated at different ionic strengths pH-metrically and the data were utilized to estimate the thermodynamic stability constants at zero ionic strength and to know the exact nature of the complexation equilibria. The different possible reactions and expected values of DZ2 for corresponding dissociation or association equilibria are determined.

KEYWORDS:

Ionic strength; stability constants; Bronsted equation; salt effect

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Copy the following to cite this article: Deosarkar S. D, Narwade M. L, V. J., Hiwase V. V, Khedkar K. M. Influence of Ionic Strength of Medium on Stability Constants of Cu(II) Complex of 2-Amino-5-Chloro Benzene Sulphonic Acid at 301K. Orient J Chem 2009;25(1).

Copy the following to cite this URL: Deosarkar S. D, Narwade M. L, V. J., Hiwase V. V, Khedkar K. M. Influence of Ionic Strength of Medium on Stability Constants of Cu(II) Complex of 2-Amino-5-Chloro Benzene Sulphonic Acid at 301K. Orient J Chem 2009;25(1). Available from: http://www.orientjchem.org/?p=23407