Studies on Binary Complexes of Cu(Ii)/ Uo2(Ii)/Ni(Ii)/ Co(Ii)/ Zn(Ii)/ Cd(Ii) by Paper Electrophoresis

Padmakshi Singh and Satyendra Singh

Kashi Naresh Govt. Post Graduate College, Gyanpur, Bhadohi - 221 304 India.

ABSTRACT:

Stability constants ML and ML2 type binary complexes of Cu (II)/ UO2(II)/ Ni(II)/ Co(II)/ Zn(II)/ Cd (II), 8-Azaguanine system is determined by paper electrophoresis. The technique is based on the movement of a spot of metal ion under an electric field with the change of pH of back ground electrolyte at ionic strength 0.1 M perchloric acid. The stability constant of the ML and ML2 complexes of metal - 8-Azaguanine have been found to be (7.65, 5.50), (7.38, 5.75), (5.64, 3.82), (5.75, 3.68), (5.33, 4.21) and (4.45, 3.73) for Cu (II)/ UO2(II)/ Ni(II)/ Co(II)/ Zn(II)/ Cd (II) complexes respectively.

KEYWORDS:

Paper Electrophoresis; Stability constant; mobility

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Copy the following to cite this article: Singh P, Singh S. Studies on Binary Complexes of Cu(Ii)/ Uo2(Ii)/Ni(Ii)/ Co(Ii)/ Zn(Ii)/ Cd(Ii) by Paper Electrophoresis. Orient J Chem 2008;24(1).

Copy the following to cite this URL: Singh P, Singh S. Studies on Binary Complexes of Cu(Ii)/ Uo2(Ii)/Ni(Ii)/ Co(Ii)/ Zn(Ii)/ Cd(Ii) by Paper Electrophoresis. Orient J Chem 2008;24(1). Available from: http://www.orientjchem.org/?p=23295