Bi and Trivalent Transition Metal Complexes of Dithiocarbamates Derived from 2,6- Diacetyl Pyridine

Mohammad Tarique and Mohammad Aslam*

Department of Chemistry, Gandhi Faiz-e-Aam (P.G.) College, Shahjahanpur - 242 001 India.

ABSTRACT:

Some new 3d-series transition metal complexes of types ML{M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M’2L3 {M’=Cr(III) and Fe(III)} with dithiocarbamate ligand derived from 2,6-diacetyl pyridine have been prepared by the replacement reaction method. These complexes have been characterized by elemental analysis, conductivity measurements and infrared spectral studies. All the complexes were non-electrolyte in nature. Infrared spectral data of these complexes showed the bidentate behaviour of ligand and the metals were found to be tetra and hexa-coordinated in ML and M’2L3 type of complexes respectively.

KEYWORDS:

Bi and trivalent transition metal complexes; dithiocarbamates

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Copy the following to cite this article: Tarique M, Aslam M. Bi and Trivalent Transition Metal Complexes of Dithiocarbamates Derived from 2,6- Diacetyl Pyridine. Orient J Chem 2008;24(1).

Copy the following to cite this URL: Tarique M, Aslam M. Bi and Trivalent Transition Metal Complexes of Dithiocarbamates Derived from 2,6- Diacetyl Pyridine. Orient J Chem 2008;24(1). Available from: http://www.orientjchem.org/?p=23297