Synthesis and Characterisation of Methylene Bis Thioacetamido Diphenyl and its Complexes With Co(Ii), Fe(Iii), Zn(Ii), Cd(Ii) and Hg(Ii)
Chandra Has1, Y.P. Varshney1, U.C. Sharma2 and L.K. Sharma2
1Research Laboratory, Department of Chemistry, S.V. College, Aligarh (India) 2Department of Chemistry, V.A. Government Degree College, Atrauli, Aligarh (India)
Methylene bis thioacetamido diphenyl (MBTAD) C17H18N2S2O2, a new chelating agent and its complexes with Co(II), Fe(III), Zn(II), Cd(II) and Hg(II) have been synthesised and characterised by different techniques like elemental analysis, magnetic moment, I.R. and electronic spectral studies etc. MBTAD forms thermally quite stable complexes of ML2 type. It forms square planar complex with Co(II), octahedral complex with Fe(III) and diamagnetic tetrahedral complexes with Zn(II), Cd(II) and Hg(II).
KEYWORDS:Methylene bis thioacetamido diphenyl; chelating agents; complexes
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| Copy the following to cite this article: Has C, Varshney Y. P, Sharma U. C, Sharma L. K. Synthesis and Characterisation of Methylene Bis Thioacetamido Diphenyl and its Complexes With Co(Ii), Fe(Iii), Zn(Ii), Cd(Ii) and Hg(Ii). Orient J Chem 2005;21(3). |
| Copy the following to cite this URL: Has C, Varshney Y. P, Sharma U. C, Sharma L. K. Synthesis and Characterisation of Methylene Bis Thioacetamido Diphenyl and its Complexes With Co(Ii), Fe(Iii), Zn(Ii), Cd(Ii) and Hg(Ii). Orient J Chem 2005;21(3). Available from: http://www.orientjchem.org/?p=19229 |
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