Synthesis and Spectroscopy of New Palladium(Ii) and Zirconium(Iv) Complexes Containing Binucleating Indeyl-and Bis(Indenyl)Ethane-Phosphine Ligands
Adnan S. Abu-Surrah* and Hamzah Abdel-Halim
Department of Chemistry, Hashemite University, P.O. Box- 150459 Zarqa- 13115 (Jordan)
New palladium(II) complexes (4 and 5) and zirconium(IV) complexes (6 and 7) bearing the binucleating indenyl-phosphine ligands; 1-h5-indenyl-2-diphenyl phosphinoethane (IND-PPh2, 2) and 1,2-bis(h5-(3-diphenyl-phosphinoethyl)indenyl)ethane (BINDE-PPh2, 3) were prepared and characterized. Reaction of [Zr(IND-PPh2)Cl2] (6), which contains the unbridged, binucleating ligand 2, with [Pd(NCPh)2Cl2] afforded the heterobimetallic Zr(IV)-Pd(II) complex 8.
KEYWORDS:Palladium(II) complexes; Zirconocene complexes; Bisindenyl ligands; Diphosphine ligands; Binucleating ligands; Bimetallic complex
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| Copy the following to cite this article: Abu-Surrah A. S, Abdel-Halim H.Synthesis and Spectroscopy of New Palladium(Ii) and Zirconium(Iv) Complexes Containing Binucleating Indeyl-and Bis(Indenyl)Ethane-Phosphine Ligands. Orient J Chem 2004;20(2). |
| Copy the following to cite this URL: Abu-Surrah A. S, Abdel-Halim H.Synthesis and Spectroscopy of New Palladium(Ii) and Zirconium(Iv) Complexes Containing Binucleating Indeyl-and Bis(Indenyl)Ethane-Phosphine Ligands. Orient J Chem 2004;20(2). Available from: http://www.orientjchem.org/?p=18489 |
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