ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Synthesis and Spectral Studies of Thorium (Iv) and Dioxouranium (Vi) Complexes of A Schiff Base Ligand

Kishor Aroraa, K. P. Sharmab and A. R. Khanc*

1Department of Chemistry, Government Autonomous K.R.G. College, Gwalior - 474 001 (India) 2Department of Chemistry, Government Science College, Gwalior - 474 001 (India) 3Department of Chemistry, Government Post-Graduate College, Sheopur (India)

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ABSTRACT:

A new series of Th(IV), UO2(VI) with a schiff base derived from condensation of o-methyl aniline and p-(N, N'-dicyanoethyl) amino benzaldehyde having general composition, THX4.nL (X=NO3-, n=2; X=NCS-, n=2, X=I-, n=4; X=ClO4-, n=6) and UO2X2.2L (X=NO3-, I-, NCS- or CH3COO-) and UO2(ClO4)2.4L where L is the schiff base. The complexes were characterized on the basis of analytical conductance molecular weight and spectral studies. The schiff base behaves as a neutral monodentate ligand which coordinate to the central metal atom through azomethine nitrogen.

KEYWORDS:

Dioxouranium (VI) complexes; Schiff bases; Throium (IV)

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Aroraa K, Sharmab K. P, Khanc A. R. Synthesis and Spectral Studies of Thorium (Iv) and Dioxouranium (Vi) Complexes of A Schiff Base Ligand. Orient J Chem 2003;19(2).


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Aroraa K, Sharmab K. P, Khanc A. R. Synthesis and Spectral Studies of Thorium (Iv) and Dioxouranium (Vi) Complexes of A Schiff Base Ligand. Orient J Chem 2003;19(2). Available from: http://www.orientjchem.org/?p=17903"



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