ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
     FacebookTwitterLinkedinMendeley

Photo-Oxidation of Ammonium Pyrrolidine Dithiocarbamate by Uranyl Ions

Volume 19, Number 2

Neelam Jain, B. V. Kabra and R. L. Pitliya

Department of Chemistry, M. L. V. Government College, Bhilwara 311 001 (India)

Article Publishing History
Article Received on :
Article Accepted on :
Article Metrics
ABSTRACT:

Photo-oxidation of ammonium pyrrolidine dithio carbamate by uranyl ions in presence of perchloric acid has been studied, at pH 2.0. Pyrrolidine-2-carboxylic acid, sulphur, sulphurdioxide and ammonia have been characterized as the photoproducts. The intermediacy of U (V) has been proved spectrophotometrically. A mechanism has been proposed involving excited state charge transfer complex (exciplex) formation.

KEYWORDS:

Photo-oxidation; Ammonium pyrrolidine dithiocarbamate and Uranyl ions

Download this article as: 

Copy the following to cite this article:

Jain N, Kabra B. V, Pitliya R. L. Photo-Oxidation of Ammonium Pyrrolidine Dithiocarbamate by Uranyl Ions. Orient J Chem 2010;26(1).

Copy the following to cite this URL:

Jain N, Kabra B. V, Pitliya R. L. Photo-Oxidation of Ammonium Pyrrolidine Dithiocarbamate by Uranyl Ions. Orient J Chem 2010;26(1). Available from: http://www.orientjchem.org/?p=23725

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

About The Author