ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Separation of Yttrium and Uranium from Xenotime Using Poly(Hydroxamic Acid) Chelating Ion Exchange Resin

M. J. Haron1, W. M. Z. Wan Yunus2, P. C. Yap1, M. A. Sukari1 and M. Y. M. Sulaiman2*

1Chemistry Department, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia) 2Malaysian Institute for Nuclear Technology Research (MINT), 43000 Kajang, Selangor, (Malaysia)

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ABSTRACT:

Poly(hydroxamic acid) chelating ion exchange resin (PHA) was found able to sorb uranium (VI) with a higher capacity compared to yttrium (III) in sodium acetate buffer solution at pH 4. Yttrium (III) and uranium (VI) from leached solution of xenotime sample was separated after passing it through the column packed with the ion exchanger. The yttrium (III) was eluted with buffer solution at pH 4 while the resin retained the uranium (VI). The uranium (VI) was eluted from the column with 2M nitric acid.

KEYWORDS:

Poly hydroxamic acid; xenotime; ion exchange resin

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Haron M. J, Wan Yunus W. M. Z, Yap P. C, Sukari M. A, Sulaiman M . Y. M . Separation of Yttrium and Uranium from Xenotime Using Poly(Hydroxamic Acid) Chelating Ion Exchange Resin. Orient J Chem 2001;17(2).


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Haron M. J, Wan Yunus W. M. Z, Yap P. C, Sukari M. A, Sulaiman M . Y. M . Separation of Yttrium and Uranium from Xenotime Using Poly(Hydroxamic Acid) Chelating Ion Exchange Resin. Orient J Chem 2001;17(2). Available from: http://www.orientjchem.org/?p=16288



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