Non-Isothermal Kinetic Parameters of Decomposition of Morpholino Thiosemicarbazone Nickel (II) Chloride

Birendra Kumar Singh, Ranjeet Kumar Sinha and D. Prakash

Department of Chemistry, Patna University, Patna - 800 005 India.

ABSTRACT:

The first stage of non-Isothermal decomposition of Morpholino thiosemicarbazone of Nickel (II) chloride at a constant heating rate of 10°C min-1  was studied. The kinetic parameters have been measured using Freemann - Carroll and Zsako methods. The values of energy of activation, order of reaction were found to be 37.6082 K.Cal./mole and 1.85 respectively from Freemann and Carroll method and 38.000 K.Cal./mole and 2.00 respectively from Zsako method. The values of frequency factor and activation entropy were found to be 8.81729 x 1011 sec-1 and 21.9498 e.u. respectively.

KEYWORDS:

Morpholino; thiosemicarbazone; Isothermal Zsako

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Copy the following to cite this article: Sinha R. K, Prakash D. Non-Isothermal Kinetic Parameters of Decomposition of Morpholino Thiosemicarbazone Nickel (II) Chloride. Orient J Chem 1998;14(1).

Copy the following to cite this URL: Sinha R. K, Prakash D. Non-Isothermal Kinetic Parameters of Decomposition of Morpholino Thiosemicarbazone Nickel (II) Chloride. Orient J Chem 1998;14(1). Available from: http://www.orientjchem.org/?p=21646