Thermodynamic Relationships In Complex Formations , VIII. ΔH - ΔS Behaviour In Series Of Reactions Of Polyamines With Proton Or Metal Ions Inaqueous Solution
Domenico De Marco1, Antonlno Giannetto1 and Elzebieta Lodyga-Chruscinska2
1Department of Inorganic Analytical Chemistry and Molecular Structure. University of Messina.Salita Sperone 31 .CP 30.98166 S Agata, Messina, Italy. 2Institute of General Food Chemistry.Technical University of Lodz. Stefanowskiego 4/10.90924 Lodz .., Poland.
Article Received on : December 15,1996
Article Accepted on :
ΔH - ΔS patterns tor senes of protonation or complex formation reactions of ethytendiamine related tri tetra- and peniamine in aqueous solution have been inspected in order to verify the occurence of tuncaonat tetetionsNps between the two parameters. Both the senes of reactions of variabie divalent metal ions with constant ligand and the series of protonation of different polyamines do not show functional behaviours and emphasise the occurence of specific interactions which intervene for specific structural characteristics of the ligandes.
KEYWORDS:ΔH - ΔS relationships; Isoequiltbrium; Polyaminas
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| Copy the following to cite this article: Marco D. D, Giannetto A, Lodyga-Chruscinska E. Thermodynamic Relationships In Complex Formations , VIII. ΔH - ΔS Behaviour In Series Of Reactions Of Polyamines With Proton Or Metal Ions Inaqueous Solution. Orient J Chem 1997;13(1). |
| Copy the following to cite this URL: Marco D. D, Giannetto A, Lodyga-Chruscinska E. Thermodynamic Relationships In Complex Formations , VIII. ΔH - ΔS Behaviour In Series Of Reactions Of Polyamines With Proton Or Metal Ions Inaqueous Solution. Orient J Chem 1997;13(1). Available from: |
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