E P R of Cu2+ Ion in Bisglycine Strontium Chloride Trihydrate Single Crystals

S. Dhanuskodi

Department of Physics, Bharathidasan University. Tiruchirapalli 620 024 India.

ABSTRACT:

E P R spectra of Cu2+ doped bisglycine strontium chloride trihydrate single crystals which represents one of the few examples of nine coordinated systems, are recorded at room temperature at X-band frequencies. The analysis of the spectra show that Cu2+ ion enters the lattice sbstitutionalu in the place of Sr2+ ion. The spin-Hamiltonian parameters obtained from the measurements are used to calculate the bonding parameters and it is found that the ground state wave function of Cu2+ ion is an admixture I3z2 - r2 > and lx2 - y2 > orbitals.

KEYWORDS:

Cu2+, Spin-Hamiltonia; Measurements

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Copy the following to cite this article: Dhanuskodi S. E P R of Cu2+ Ion in Bisglycine Strontium Chloride Trihydrate Single Crystals. Orient J Chem 1996;12(1).

Copy the following to cite this URL: Dhanuskodi S. E P R of Cu2+ Ion in Bisglycine Strontium Chloride Trihydrate Single Crystals. Orient J Chem 1996;12(1). Available from:http://www.orientjchem.org/?p=37664