Abstract
Kinetics and Thermodynamics of Oxidation of Some Meta-Substituted Anilinesby Tetrabutylammoniumbromochromatein Aqueous Acetic Acid Medium
Shaik Jabir1, Basim H. Asghar2 and S. Sheik Mansoor3
DOI : http://dx.doi.org/10.13005/ojc/330134
Abstract:
The tetrabutylammoniumbromochromate(TBABC) oxidation of anilines, in anaqueous acetic acid mediumin the presence of perchloric acid is described. The reaction is first order with respect to aniline, TBABC and acid. The reaction rate has been determined at different temperatures and activation parameters calculated. The TBABC oxidation of meta-substituted anilines obeys Hammett relationships
Keywords:tetrabutylammoniumbromochromate;aniline; thermodynamic parameters; kinetics
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