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Effect of Solvent on the Formation of Transition Metal Complexes of Tridentate Schiff Base

Dev Das Manwa1l and A. V. Chandra Pal2

1Department of Chemistry, Nizam College Hyderabad-500 01 India 2Department of Chemistry, Osmania University, Hyderabad-500 007 India

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ABSTRACT:

Potentiometric equilibrium measurements have been carried out at 30°C in different proportions (40, 50,60 & 70% v/v) of methanol-water mixture for the formation of binary complexes of Cu (II), Ni (II), Co (II), ZQ (II) and 2-[ [ (lH-benzimidazol-2-ylmethyl) imino] methyl] phenol (BMIMP). The ionic strength was maintained constant by using 0.1 M NaClO4 as the supporting electrolyte. Stabilities of these complexes increase with an increase in methanol content.

KEYWORDS:

Transition; Complexes; Tridentate

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Manwa D. D, Pal A. V. C. Effect of Solvent on the Formation of Transition Metal Complexes of Tridentate Schiff Base. Orient J Chem 1992;8(3).


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Manwa D. D, Pal A. V. C. Effect of Solvent on the Formation of Transition Metal Complexes of Tridentate Schiff Base. Orient J Chem 1992;8(3). Available from: http://www.orientjchem.org/?p=38972



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