Stereochemistry of Some N- [2-Methyl-1-(1-Naphthyl) Propylidene] Arylamines


Salim S. Al-Showiman
Department of Chemistry, College of Science, King Saud University, P. 0. Box 2455, Riyadh 11451 Saudi Arabia.

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ABSTRACT:

The stereochemistry of the title compounds has been assigned on the basis of their 1H and 13C NMR data. These imines were found to exist in solution exclusively in the Z-Configuration. The geminal C-isopropyl mehtyls were found to be isochronous indicating low rotational barrier around the 1-naphthyl-imino bond.

KEYWORDS:

Stereochemistry; Propylidene; Arylamines


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