Synthesis and Characterization of New Rhodium Nitrosyl Complexes with General Formula [RhX2 (NO) L2] (X = Cl, Br, PPh3, PEtPh2 and Pet2Ph)

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Synthesis and Characterization of New Rhodium Nitrosyl Complexes with General Formula [RhX2 (NO) L2] (X = Cl, Br, PPh3, PEtPh2 and Pet2Ph)

Suneeta Singh¹, K. K. Singh² and J. P. Singh¹*

¹Department of Chemistry, S.G.R.P.G. College, Dobhi, Jaunpur - 222 149 (India). ²Department of Chemistry, T.D.P.G. College, Jaunpur (India).

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ABSTRACT:

The reaction of nitrosothiourea were carried out with [RhHX₂L₂] (X = Cl, Br; L = PPh₃, PEtPh₂ and PEt₂Ph) in alcohol. The product were purified, analysed and characterized on the basis of analytical, spectral (IR, UV and Visible) and magnetic studies. A tentative structure to all the complexes have been proposed.

KEYWORDS:

New Rhodium Nitrosyl complex; IR; UV and Visible studies