Synthesis and Characterization of some CIS [Ru(NO)XL2(PPh3)2 (X=Monodentate) Type Complexes of Nitrosylrutheitum (II)
1Department of Chemistry S.G.R. Post Graduate College, Dobhi, Jaunpur - 222 149 (India).
2Department of Chemistry, T.D. Post Graduate College, Jaunpur (India).
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Nitrosyl complexes which have both L= methyl cyanide and triphenylphosphine as coexisting ligands were synthesized and characterised as cis [Ru(NO)(X)L2(PPh3)2]+2 X= OH,Cl,NO2 and L=CH3CN). The structures of the complexes have been proposed on the basis of analytical, magnetic and spectroscopic (IR, UV-Visible and 1H NMR) methods. The properties of these complexes were investigated under the conditions of chemical oxidation and electrochemical reduction.
KEYWORDS:Nitrosylrutheitum (II); Spectroscopic methods; Chemical oxidation
