Synthesis and Characterization of New Ruthenium – Aromatic Thioamide Nitrosyls

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Synthesis and Characterization of New Ruthenium – Aromatic Thioamide Nitrosyls

T. Singh and K. K. Singh¹

¹Department of Chemistry S.G.R. Post Graduate College, Dobhi, Jaunpur - 222 149 (India) ²Department of Chemistry, T.D. Post Graduate College, Jaunpur (India).

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ABSTRACT:

Reactions of aromatic thioamides, LH, with [Ru(NO)Cl3(PPh3)2] yields [Ru(NO)Cl3(LH)]. The complexes have been characterized by analytical, IR, U.V and Visible spectral and magnetic measurements. The presence of u(NO) at 1830- 1840 cm-1 indicates a {Ru NO}6 configuration.

KEYWORDS:

Synthesis; ruthenium and thioamide nitrosyls