IR and PMR spectral studies on complex derivatives of heterocyclic thioamides with metal-metal bond

R.N. Pandey; Gunjan Kumari; Rajnish K. Singh

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IR and PMR spectral studies on complex derivatives of heterocyclic thioamides with metal-metal bond

R.N. Pandey*, Gunjan Kumari and Rajnish K. Singh

P.G. Centre of Chemistry (M.U.), College of Commerce, Patna - 800 020 (India).

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ABSTRACT:

A of complexes containing Hg-Hg bond with derivatives of 1-para substituted phenyl tetrazoline-5-thione have been prepared and investigated using elemental analysis, conductometric, magnetic, IR, UV-vis and 1H NMR spectra data. All thioamide ligands acts as bidentate (N,S) and no disproportionation of Hg(I) occurs during complex formation.

KEYWORDS:

Metal- Metal bond; thioamide ligands; spectral studies