Synthesis and Characterisation of Methylene Bis Thioacetamido Diphenyl and its Complexes With Co(Ii), Fe(Iii), Zn(Ii), Cd(Ii) and Hg(Ii)

Chandra Has; Y.P. Varshney; U.C. Sharma; L.K. Sharma

Article | Open Access

Synthesis and Characterisation of Methylene Bis Thioacetamido Diphenyl and its Complexes With Co(Ii), Fe(Iii), Zn(Ii), Cd(Ii) and Hg(Ii)

Chandra Has¹, Y.P. Varshney¹, U.C. Sharma² and L.K. Sharma²

¹Research Laboratory, Department of Chemistry, S.V. College, Aligarh (India) ²Department of Chemistry, V.A. Government Degree College, Atrauli, Aligarh (India)

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ABSTRACT:

Methylene bis thioacetamido diphenyl (MBTAD) C17H18N2S2O2, a new chelating agent and its complexes with Co(II), Fe(III), Zn(II), Cd(II) and Hg(II) have been synthesised and characterised by different techniques like elemental analysis, magnetic moment, I.R. and electronic spectral studies etc. MBTAD forms thermally quite stable complexes of ML2 type. It forms square planar complex with Co(II), octahedral complex with Fe(III) and diamagnetic tetrahedral complexes with Zn(II), Cd(II) and Hg(II).

KEYWORDS:

Methylene bis thioacetamido diphenyl; chelating agents; complexes