Studies on Complexes of Metal Ions With 2-(O-Carboxy Phenyl)- 3-Hydroxy-4(3h) Quinazolinone in Presence of Other Chelating Agents at Different Temperatures by Ph-Metrically

G. Satyanarayana, K. Mukkantia and B. Satyanarayanab*

¹Centre for Environment, Institute of Science and Technology Jawaharlal Nehru Technological University, Hyderabad -500 072 (India) ²Department of Chemistry, University College of Engineering Osmania University, Hyderabad-500 072 (India)

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ABSTRACT:

The formation constant of binary M(II)-CPHQO and ternary [M(II)-CPHQO-A] chelates [where M(II)=Co(II), Ni(ll), Cu(ll) and Zn(ll); CPHQO=2(o-carboxy phenyl)-3-hydroxy-4(3H)quinazolinone; A = glycine, alanine, proline, histidine, iminodiacetic acid, nitrilotriaceticacid, 2,2'-Bipyridyl and ethylenediamine] have been determined pH metrically in 10% (v/v) aq. ethanol medium at 30°C and ionic strength of I = 0.1 M KNO3. The order of formation constants of binary and ternary chelates follows lrving-William order [Co (ll)< Ni(ll)<cu(ll)>Zn(ll)]. The proton-ligand, metal ligand and ternary metal complexes formation constants also evaluated at different temperatures. Thermodynamic parameters have also been determined.

KEYWORDS:

Quinazolinone derivatives; Chelating agent; pH metric studies