Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester

Anupam Singh,; Meera Sharma; Pratibha Singh

Article | Open Access

Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester

1Anupam Singh, ¹Meera Sharma and ²Pratibha Singh

¹Department of Chemistry, Agra College, Agra (India) ²Department of Chemistry, I.B.S., Dr. B.R.A. University, Agra (India)

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ABSTRACT:

The micellar catalysed reactions of hydroxide and hydroperoxide anions with mono-2,4-dichlorophenyl phosphate has been investigated. Borate ion accelerate the reaction. The kinetic rate data in [OH-] can be accounted for quantitatively in term of the pseudophase ion exchange model, but this model fits rate data only qualitatively for reaction of [HO2-].

KEYWORDS:

Micellar catalysis; Substituted phosphate ester