Influence of Ionic Strength on the Stability Constant of Co(Ii), Sr(Ii), Pr(Iii) Complexes With Methyl [-1-Phenyl-3-(2-Hydroxy Phenyl) Pyrazole-5-Carboxylate]


P. B. Agrawal*, A. S. Burghate, Md. Idrees, Md. Siddique and M. L. Narwade
Department of Chemistry, Government V.M.V. Amravati - 444604 (India)

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ABSTRACT:

The interaction of Co(II), Sr(II), Pr(III) with methyl [-1-phenyl-3-(2’-hydroxy phenyl) pyrazole-5-carboxylate] has been studied at various ionic strengths pH metrically. The values of pk (proton-ligand stability constants) & log k (metal-ligand stability constants) are utilised to estimate the thermodynamic stability constants at zero ionic strength and to know the exact nature of complexation equilibria.

KEYWORDS:

Stability constant; complexes; pyrazole derivatives


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