Synthesis and Characterization of Dioxouranium (Vi) Complexes of Schiff Base Ligands
1Department of Chemistry, Government Auto. K.R.G. College, Gwalior - 474 002 India.
2Department of Chemistry, Government Post Graduate College, Morena - 476 001 India.
3School of Studies in Chemistry, Jiwaji University, Gwalior - 474 011 India.
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ABSTRACT:A series of 12 new complexes of dioxouranium (VI) with two schiff base ligands viz 2 N-(3-methoxy-4-hydroxy benzaiidene) amino pyridine (MHBAPy) and 2N-(Salicylidene) aminopyrkfine (SAPy) were prepared in non aqueous media having the general composition UO2X2.2L(X=N03, Br, I, NCS and CH3COO) or U02 (CIO4)24L (L=MHBAP or SAPy) and characterized on the basis of elemental analyses, electrical conductance, IR and electronic spectral studies. The X-ray diffraction studies of one of the complex has been done successfully and reported. The probable coordination number of these complexes has tentatively been assigned as 6 or 8 depending upon the nature of anions.
KEYWORDS:Dioxouranium complexes; Configuration; X-ray analysis; Synthesis.
