Studies of Dioxouranium (VI) Metal Complexes With A Schiff Base of Aminopyridine

Kishor Arora, D. P. Sharma* and M. C. Pathak

¹Department of Chemistry, Government Autonomous K.R.G. College, Gwatior India.

²Government Girls College, Morena - 476 001 India.

³Government Post Graduate College, Morena - 476 001 India.

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ABSTRACT:

A series of new diaxouranium (VI) complexes with a Schiff base derived from 2-aminopyridine has been synthesized. Analytical, spectral and i.r as well as n.m.r and antifungal studies of the complexes have been reported. Ligand was found to act as N-coordinalmg monodentate ligand coordinating through azomethlne linkage to the uranium atom. The coordination number of V-atom was found to be 6 or 8 depending upon the anions present.

KEYWORDS:

Diaxouranium; 2-aminopyridine; N-coordinalmg