ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Semi-refined κ-carrageenan: Part 1. Chemical modification of semi-refined κ-carrageenan via graft copolymerization method, optimization process and characterization of its superabsorbent hydrogel.

Jamaluddin Mohd. Daud1*, Nor Shuhadah Warzukni2, Rosliza Mohd Salim1 and Ahmad Muzammil Zuberdi2

DOI : http://dx.doi.org/10.13005/ojc/310243


Abstract:

This study was carried out for the preparation of super absorbent polymer hydrogel from semi-refined κ-carrageenan originated from Kappaphycusalvarezii (Doty) Doty ex P. Silva through graft copolymerization method with acrylic acid. The reaction was carried out in an aqueous solution in the presence of N,N-methylene bis-acrylamide as a crosslinker and ammonium persulphate as an initiator. The effect of the amount of cross linker, monomer, initiator and alkali on the swelling capacity of the hydrogel was investigated for optimum conditions.After preparing the desired hydrogel according to optimum conditions, the hydrogel was characterized by FTIR spectroscopy, SEM microscopy and swelling capacity measurement.

Keywords:

semi-refined κ-carrageenan; graft copolymerization; optimization; superabsorbent; crosslinking; swelling

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