ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Knoevenagel Condensations Catalyzed by New Oil Shale Recyclable Catalyst at Room Temperature and Assisted by Ultrasounds Irradiations

Elmustapha Ennesyry1, Fathallaah Bazi1*, Bahija Mounir1, M’hammed Elkouali1, Hassan Hannache2, Mohammed Talbi1 and Mohammed Hamza1

DOI : http://dx.doi.org/10.13005/ojc/370604


Abstract:

Functionalized alkenes were successfully synthesized via a clean procedure in a short time by using a new recycled heterogeneous catalyst prepared from Moroccan oil shale, this catalyst is characterized by different technics such XRD, BET-BJH, MEB-EDS, and TGA, before it’s has been used in the Knoevenagel condensation between different aldehydes and active methylenes. The results showed that coupling the catalyst with ultrasound irradiations could improve the catalytic system in this transformation by achieving the products in a very short time, the results showed clearly that this catalyst could be considered as excellent recyclable support in Knoevenagel condensation.

Keywords:

Heterogeneous catalysis; Knoevenagel; Oil Shale; Ultrasound

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