ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Reactions of MoCl5 with Succinimide, Imidazole, 3-Methylpyridine and 4-Methylpyridine in THF

Rakesh Kumar1 and Gursharan Singh2*

DOI : http://dx.doi.org/10.13005/ojc/370316


Abstract:

MoCl5 was reacted with succinimide/imidazole/3-methylpyridine/4-methylpyridine in THF medium using equal/double molar concentrations of the ligand at room temperature. The end products obtained are: MoO2Cl4(C4H5NO2)4(C4H8O), [1]; Mo2O12Cl7(C3H4N2)7, [2]; Mo2O12Cl7(C3H4N2)7, [3]and Mo3Cl8(C6H7N)4(C4H8O)2, [4].
The above compounds were characterized by FTIR, 1H NMR, 13C NMR, LC-MS, microbiological and C, H, N, Mo, Cl studies. All procedures and work outs were handled in vacuum line using dry nitrogen atmosphere to protect the products from oxidation/hydrolysis by air/moisture.Elemental data and fragments visualized in LC-MS are concordant with the formulae derived.

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