ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Bis-(3,5- Dimethoxy Salicylidine)-Ethylenediamine as a Gravimetric Reagent for Cu(II)

Bijay Kumar1, Santosh Kumar Sethi2 and Ashok Kumar Yadav3*

DOI : http://dx.doi.org/10.13005/ojc/360528


Abstract:

Complex of Cu(II) with bis-(3,5-dimethoxy salicylidine)-ethylenediamine was synthesized and was characterized by elemental analysis, melting point determination, conductivity measurement, magnetic property studies and spectroscopic studies. Molecular formula of the newly prepared complex was determined as C20H22N2O6Cu and the probable geometry has been suggested as square planar. Gravimetric estimation of Cu(II) was made with bis-(3,5-dimethoxy salicylidine)-ethylenediamine and the result was compared with the known method of estimation of Cu(II) iodometrically . It was found that the result of estimation with newly prepared reagent was highly satisfactory and at par with the previously reported result of estimation of Cu(II) iodometrically .

Keywords:

Bis-(3,5-Dimethoxy Salicylidine)-Ethylenediamine; With Bis-(3,5-Dimethoxy Salicylidine)-Ethylenediamine Cu(II) Complex

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