ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Studies on the Cu (II) and Co (II) complexes with N,N’–bis (2-benzothiazolyl) -2,6 pyridine dithiocarboxamides.

A. K. Srivastava*,  Swati Kumari, and Nidhi Srivastava

DOI : http://dx.doi.org/10.13005/ojc/300473


Abstract:

The ligand N,N’–bis (2-benzothiazolyl)-2,6–pyridine dithiocarboxamides and its Cu (II) and Co (II) complexes were synthesized. Their structures were elucidated on the basis of elemental analysis, analytical data, magnetic moments, electronic spectral and IR Spectral studies. The complexes were found to be monomeric and nonelectrolytic in nature. On the basis of electronic spectral studies the complexes were concluded to be distorted octahedral. The IR Spectrum suggested that the ligand behaved as uninegative bidentate ligand coordinating through nitrogen and sulphur atoms.

Keywords:

N; N’–bis(2-benzothiazolyl)-2;6–pyridine dithiocarboxamide; 2; 6–pyridine dithiocarboxylic acid; 2–aminobenzothiazole; spectral study;

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