ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Heterogeneous Zeolite-Based Catalyst for Esterification of α-Pinene to α-Terpinyl Acetate

Nanik Wijayati1,2, Ella Kusumastuti1, Dante Alighiri*1,2, Baiti Rohmawati1 and Retno Ariadi Lusiana3

DOI : http://dx.doi.org/10.13005/ojc/350150


Abstract:

The purpose of this study is to determine the most effective type of heterogeneous catalyst such as natural zeolite (ZA), Zr-natural zeolite (Zr/ZA) and zeolite Y (H/ZY) in esterification of α-pinene. α-terpinyl acetate was successfully synthesized from α-pinene and acetic anhydride by their heterogeneous catalysts. The esterification reaction was carried out with reaction time, temperature and zeolite catalysts. The most effective catalysts used in the synthesis of α-terpinyl acetate is catalyst H/ZY with the yield is 52.83% at 40°C for the time 4 hours with a selectivity of 61.38%. The results showed that the effective separation of catalyst could contribute to developing a new strategy for the synthesis of α-terpinyl acetate.

Keywords:

α-pinene; Esterification; Terpinyl Acetate; Zeolite

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