Abstract
Meso-Ionic Oxazolones in Heterocyclic Synthesis : Reactions of 4-Arylidene-2-Aryl-Δ2-Oxazolin-5-one With Amino Acids and Some Carbon Nucleophiles
M. A. El-Hashash, A. A. Afify, M. A. Syed, A. Y. Soliman and M. M. Y. Amer
Abstract:
Meso-ionic oxazolinonc reacted with aromatic amino acids namely, o, m, and p—aminoben-zoic and gave acrylamide derivatives, some of them were converted to the corresponding benzoxa-zinone derivatives by action of acetic anhydride. With aliphatic amino acids namely glycine and glutamic acid yielded also the corresponding acrylamide derivatives, the latter was converted to a new oxazolinone derivatives via treatment with AcONa or Ac20. Behaviour of these oxazolinones toward arometic hydrocarbons has been investigated.
Keywords:Meso-Ionic; Heterocyclic; Nucleophiles
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