ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Meso-Ionic Oxazolones in Heterocyclic Synthesis : Reactions of 4-Arylidene-2-Aryl-Δ2-Oxazolin-5-one With Amino Acids and Some Carbon Nucleophiles

M. A. El-Hashash, A. A. Afify, M. A. Syed, A. Y. Soliman and M. M. Y. Amer


Abstract:

Meso-ionic oxazolinonc reacted with aromatic amino acids namely, o, m, and p—aminoben-zoic and gave acrylamide derivatives, some of them were converted to the corresponding benzoxa-zinone derivatives by action of acetic anhydride. With aliphatic amino acids namely glycine and glutamic acid yielded also the corresponding acrylamide derivatives, the latter was converted to a new oxazolinone derivatives via treatment with AcONa or Ac20. Behaviour of these oxazolinones toward arometic hydrocarbons has been investigated.

Keywords:

Meso-Ionic; Heterocyclic; Nucleophiles

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