ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Mixed-Ligand Complexes of Palladium (II), Ruthenium (II), Rhodium (III) and Iridium (III) with Triphenyl Phosphine and Dibenzyl Sulphide

R. N. Pandey* and Kalpana Shahi


Abstract:

The synthesis and characterization of mixed-ligand Pd(II), Ru(II), Rh(III) and Ir(III) complexes with triphenyl phosphine and dibenzyl sulphide are reported. The complexes have been characterized by analytical, conductance, magnetic susceptibility, IR, electronic, 1H NMR and 31P NMR spectral data. Palladium (II) complex is four-corrdinated square planar and other ruthenium (II), rhodium (III) and iridium (III) are six-coordinated octahedral.

Keywords:

Pt-metals; Complexes triphenyl phosphine; Dibenzyl sulphide

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