Abstract
Highly Active Rh(I) Complexes ssed for the Catalytic Oxidation of Internal Alkenes, Terminal Alkenes and Alcohols
Varsha Sharma1* and Priyanka Sagar2
Abstract:
Rh(I) complexes of azobenzene and anthranilic acid were found moderately efficient towards the catalytic oxidation of internal alkenes, terminal alkenes, and alcohol in C2H5OH-CH2Cl2 (1:1) mixed solvent system both under normal and high pressure of molecular oxygen. No diminished catalytic activity was observed even after 6-8 repeated catalytic runs. Effect of extra ligand on the rate of oxidation,nature and percentage yield of products was investigated.
Keywords:Rh(I) complexes; Catalytic oxidation; Internal alkene; Terminal alkene; Alcohol
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