ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Highly Active Rh(I) Complexes ssed for the Catalytic Oxidation of Internal Alkenes, Terminal Alkenes and Alcohols

Varsha Sharma1* and Priyanka Sagar2


Abstract:

Rh(I) complexes of azobenzene and anthranilic acid were found moderately efficient towards the catalytic oxidation of internal alkenes, terminal alkenes, and alcohol in C2H5OH-CH2Cl2 (1:1) mixed solvent system both under normal and high pressure of molecular oxygen. No diminished catalytic activity was observed even after 6-8 repeated catalytic runs. Effect of extra ligand on the rate of oxidation,nature and percentage yield of products was investigated.

Keywords:

Rh(I) complexes; Catalytic oxidation; Internal alkene; Terminal alkene; Alcohol

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