ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Synthesis and Characterization of 2-[2-Aryltelluroethyl] -3-Methyl Pyridines (Te,N) and 2-[2-(3-Methyl Pyridoethyltelluro) Ethyl]-3-Methyl Pyridine (N,Te,N)

K. K. Sharma1, Prarthana Srivastava2, Pragya3 and Kumud4


Abstract:

The potentially bidentate hard and soft acid containing (Te,N) compounds, 2-(2-aryltelluroethyl)-3-methyl pyridines (L) [C14H15NTe] and tridentate(N,Te,N) 2-[2-(3-methyl pyridoethyltelluro)ethyl]-3-methyl pyridine (L’) [C16H20 N2Te] have been synthesized in good yield ( > 75%) and characterized by physical, analytical and spectroscopic [1H, 13C{1H} and 125Te{1H} NMR and IR ] methods. The reaction of methyl iodide with L [C14H15NTe] results in the formation of the salt of the type ArTe (CH2) 2-2-(C5H4N)+. CH3I with affecting the tellurium moiety.

Keywords:

Ligands (Te, N) and (N, Te, N); IR spectra; NMR spectra

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