ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Synthesis and Characterization of Mercury(Ii) Complexes Containing Mixed Ligands of Mono or Diphosphines and Saccharinate

Shihab A.O. Al-Dury and Subhi A. Al-Jibori*


Abstract:

Tetrahedral mercury(II) complexes of the types [HgCl(sac)(PPh3)2], [HgCl(sac)(diphos)], [Hg(sac)2(PPh3)2] or [Hg(sac)2(diphos)] and octahedral complexes of the type [Hg(sac)2(dppe)2] or [Hg(sac)2(dppp)2] {diphos = Ph2P(CH2)nPPh2; n=1, dppm; n=2, dppe; n=3, dppp; n=4,dppb} were prepared and characterized by molar conductance, elemental analysis, infrared spectra, 1H and 31P-{1H} nmr data.

Keywords:

Mercury; Saccharinate; Diphosphine

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