ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Determination of Stability Constants of Thallium(I) Complexes with Amino Acids by Deford and Hume’s Method in Aqueous Medium

Jyoti Singh, Anita Kajala and O.D. Gupta


Abstract:

The stability constants of complexes formed by Thallium (I) with Serine and Leucine have been investigated in aqueous medium, the complex with metal Serine as 1:1, 1:2 and complexes of the Tl(I) with Leucine as 1:1, 1:2 have been reported. The values of formation constant of Serine are log b1 = 2.1760, log b2 = 3.85325 at 308K and log b1 = 1.9030, log b2 = 3.6739 at 318K and complexes of Tl(I) with Lecucine have log b1 = 4.0290, log b2 = 5.2922 at 308K and log b1 = 3.4772, log b2 = 4.4151 at 318K, respectively were calculated by DeFord and Hume’s method.

Keywords:

Thallium(I); serine; leucine; D.M.E.; polarographic study

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