ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Synthesis and Structural Elucidation of Complexes of Some 3d-Series Divalent Transition Metals with 2-hydroxy-4-nitro acetophenone hydrazone, Schiff Base Ligand

Prem Mohan Mishra

DOI : http://dx.doi.org/10.13005/ojc/290241


Abstract:

The ligand 2 – hydroxy – 4 - nitro acetophenone hydrazone was synthesized by the condensation reaction.Complexes of Co(II), Ni (II) and Cu(II) was prepared by refluxing metal salts with the ligands.Properties of complexes have been studied by elemental analysis, study of solubility, decomposition temperature, magnetic susceptibility, electrical conductivity, electronic and IR spectra of ligands and complexes.On the basis of the experimental results probable structures of all the metal complexes have been proposed.

Keywords:

Synthesis; structure; complex compound 2 – Hydroxy – 4 – nitroacetophenone hydrazone; Co (II); Ni(II); Cu(II); Schiff’s base; Elemental analysis; Electronic spectra; IR spectra

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