Abstract

Kishor Aroraa, K. P. Sharmab and A. R. Khanc*

A new series of Th(IV), UO2(VI) with a schiff base derived from condensation of o-methyl aniline and p-(N, N'-dicyanoethyl) amino benzaldehyde having general composition, THX4.nL (X=NO3-, n=2; X=NCS-, n=2, X=I-, n=4; X=ClO4-, n=6) and UO2X2.2L (X=NO3-, I-, NCS- or CH3COO-) and UO2(ClO4)2.4L where L is the schiff base. The complexes were characterized on the basis of analytical conductance molecular weight and spectral studies. The schiff base behaves as a neutral monodentate ligand which coordinate to the central metal atom through azomethine nitrogen.

Dioxouranium (VI) complexes; Schiff bases; Throium (IV)

[ View HTML Full Text]