ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Study of Effect of Variation of Ionic Strength of the Medium on Velocity Constant of Ru(Iii) Catalyzed Oxidation of Hydroxy Benzoic Acids by Chloramine-T in Acidic Medium

Dr. Parmod Kumar

DOI : http://dx.doi.org/10.13005/ojc/290427


Abstract:

In the present study the effect of variation of ionic strength of the medium on rate of oxidation of hydroxy benzoic acids as its effect provides some clues regarding the nature of reactive species involved in the rate determining step. In order to realize the above aim the experiments has been carried out which ultimately concluded that ionic strength variation does not change the reaction velocity constant significantly.

Keywords:

Ortho-hydroxy bezoic acid (0-HBA); meta-hydroxy bezoic acid (m-HBA); para-hydroxy bezoic acid (p-HBA); Ruthenium chloride (Ru(III)); Chloramine-T (CAT); perchloric acid (HClO4); Pottassium chloride (Kcl); sodium perchlorate (Naclo4).

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