Novel Mixed Ligand Cyano Nitrosyl Complexes of Chromium with Alkyl and Alkoxy substituted Anilines

R. C Maurya; D. C. Gupta; R. K. Shukla; N. Anandam; M. R. Maurya; R. Shukla

Article | Open Access

Novel Mixed Ligand Cyano Nitrosyl Complexes of Chromium with Alkyl and Alkoxy substituted Anilines

R. C Maurya, D. C. Gupta, R. K. Shukla, N. Anandam, M. R. Maurya*, R. Shukla

Department of Chemistry, Alarm P. G, College., Atarra-210 201 (India) Department of Chemistry, Roorkee University. Roorkee-247672 (India)

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ABSTRACT:

Several new hexacoordinated mixed ligand cyano nitrosyl complexes of chromium (I), [Cr NO (CN)2 (L)2 (H2O)] (L=2-3.or 4-ethylaniline. 2. 6-diethylaniline. 2. 4-, 2, 6-. 3, 4- or 3, 5* dimethoxyaniline) have been synthesized and characterised by elemental analyses, molar conductance molecular weight* magnetic measurement. Infrared and electron spin resonance studies. An octahedral structure has been proposed for the complexes. Chromium (I) has a low-spin d5 configuration in these complexes.

KEYWORDS:

Mixed; Ligand; Cyano;Alkoxy; substituted; Anilines