Synthesis and Characterization of Binuclear Copper(II) Complexes With two Expanded Porphyrins

S. Amani

Arak University, Department of Chemistry, Beheshti Ave, Arak 37156 Iran.

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ABSTRACT:

Two complexes of type [Cu2](macrocycle)] where macrocycles, so called " expanded porphyrins m have been synthesized, and their properties investigated. Electron Spin Resonance (ESR) spectra indicate copper(ll)-porphyrin interaction which is observed at about 3300 G. The observation of mass spectra show a binuclear copper(ll) complexes.

KEYWORDS:

Characterization; Complexes; [Cu2](macrocycle)]