Electron Spin Resonance and X-Ray Spectral Studies of Oxovanadium Complexes of Bidentate Ligand


S. D. Kolwalkar and B. H. Mehta
Department of Chemistry, University of Mumbai, Vidyanagri, C. ST. Road, Santacruz (E), Mumbai 400 098 India.

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ABSTRACT:

The four oxovanadium complexes of bidentate Schiff's base ligands have been prepared by refluxion precipitation method at optimum pH. These complexes are characterised by their electron spin resonance and X-ray spectra. In most of the cases the unpaired electron is observed in the dx2-y2 orbital.

KEYWORDS:

Oxovanadium Complexes - ESR-X RAY-STUDY


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