Synthesis and Characterization of Transition Metal Complexes of Some Triazole and Thiosemicarbazone Derivatives

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Transition metals: Mn(ll), CO(ll), Ni(ll), Cu(ll), Rh(lll) and Pd(ll) complexes of 5-Benzoylbenzo-1,2,3-triazole and 5-Benzoylbeniimidazole thiosemicarbazone were prepared and studied by elemental analysis, IR electronic spectra and thermogravimetric analyses. The measurements suggest octahedral structure for cobalt, manganese and rhodium complexes whereas square-planar configurations are proposed for copper and palladium complexes.

thermogravimetric; palladium; Benzoylbeniimidazole thiosemicarbazone