Preparation and Characterization of Some Addition Complexes of Cobalt(II) Dithioacetylacetonate with Nitrogen Donors


Renu Sachar and Suvercha Sharma*  
Department of Chemistry, University of Jammu, Babasaheb Ambedkar Road, Jammu - 180 006 India.

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ABSTRACT:

A series of 1:1 addition complexes of Cobalt(II)dithioacetylacetonates with nitrogen donors such as morpholine, piperidine, piperazine, carbazole, dimethylamine, diethylamine and isopropylamine have been synthesized by treating the appropriate metal(II)dithioacetylacetonate with nitrogen donors in organic solvent . These addition complexes have been characterized by analytical data, electrical conductance, magnetic susceptibility measurements and electronic and infrared spectral studies. The biological activities of the complexes have also been carried out and they have been found to be antifungal in nature. NMR studies of some complexes has also been carried out.

KEYWORDS:

Cobalt (II) dithioacetyl acetonate; nitrogen donors


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