Complexation of zinc and copper with 4-4’diaminodiphenyl sulfone (Dapsone)


Salil Sharma1, S. A. Iqbal1 and Mamta Bhattacharya2

1Department of Chemistry, Saifia College of Science and Education, Bhopal - 462 001 (India).

 2Department of Chemistry, S. V. College, Bairagarh, Bhopal - 462 030 (India).

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ABSTRACT:

Transition metal complexes of Cu(II) and Zn(II) have been synthesized with the drug Dapsone that is 4-4’diaminodiphenyl sulfone. Conductometric studies and elemental analysis suggest the ML2 stoichiometry. Molar conductance values indicate the non-electrolytic nature of the complexes. The ligand behaves as bidentate and forms co-ordinate bond through azomethine nitrogen. The structure assigned to the complexes, synthesized via Schiff base formation is supported by infrared spectral studies.

KEYWORDS:

Schiff base; antibacterial; Dapsone; and Infrared spectroscopy


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