Volume and Transport Properties of Binary Liquid Mixtures of Propyl Acetate With Methanol, Ethanol and Propan-1-Ol At 298.15 and 303.15 K

Bhatu S. Desale¹, Apoorva P. Hiray², Mehdi Hasan² and Hari A. Pati^l3

¹Arts, Science and Commerce College, Manmad - 423 104 (India) ²P.G. Department of Chemistry. M.S.G.College Malegaon (India) ³P.G. Department of Chemistry. Jaihind College, Dhule (India)

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ABSTRACT:

The densities and viscosities of binary mixtures of propyl acetate with methanol, ethanol and propan-1-ol have been measured over the entire range of composition at 298.15 and 303.15 K and at atmospheric pressure. Excess Gibbs free energy of activation of viscous flow ( G*E) and Grunberg-Nissan interaction parameter ( d ) of binary liquid mixtures is useful in understanding the nature of intermolecular interactions between two liquids.

KEYWORDS:

Density, viscosity; Grunberg-Nissan interaction parameter; propyl acetate; methanol; ethanol; propan-1-ol